SodiumSaturationFluidProperties

Fluid properties for liquid sodium at saturation conditions

Description

The SodiumSaturationFluidProperties class provides fluid properties for _saturated_ liquid sodium based on correlations used in the SAS4A/SASSYS-1 reactor dynamics and safety analysis code developed at Argonne National Laboratory for liquid metal reactors Dunn (2017). These property models are obtained as fits to experimental data, with computational efficiency motivating the use of a simpler functional fits than proposed in the original references upon which the SAS4a/SASSYS-1 implementation is based, namely Fink and Leibowitz (1979). Only for CpC_p and CvC_v are the original correlations/data used, since the SAS4A/SASSYS-1 implementation does not differentiate between CpC_p and CvC_v for the saturated liquid.

Density is calculated as an empirical fit to two saturated liquid density correlations recommended by Fink and Leibowitz that cover the range 371<T(K)<2509371 < T (K) < 2509:

ρ=1.00423×1030.21390T1.1046×105T2\rho=1.00423\times10^3-0.21390T-1.1046\times10^{-5}T^2

This equation fits the Fink and Leibowitz models to within 9.5%.

The thermal conductivity is a fit to experimental data by Fink and Leibowitz below 1500 K, and extrapolated values above 1500 K based on a method described by Grosse Dunn (2017):

k=1.1045×1026.5112×102T+1.5430×105T22.4617×109T3k=1.1045\times10^2-6.5112\times10^{-2}T+1.5430\times10^{-5}T^2-2.4617\times10^{-9}T^3

This equation fits the Fink and Leibowitz data to within 0.5%.

The dynamic viscosity is given as a fit to experimental data by Fink and Leibowitz below 1200 K and extrapolated values about 1200 K based on a method described by Grosse Dunn (2017):

μ=3.6522×105+0.16626T4.56877×101T2+2.8733×104T3\mu=3.6522\times10^{-5}+\frac{0.16626}{T}-\frac{4.56877\times10^1}{T^2}+\frac{2.8733\times10^4}{T^3}

This equation fits the Fink and Leibowitz data to within 0.5%.

The isobaric and isochoric specific heats are obtained as new fits to the experimental data in Fink and Leibowitz over the range 400<T(K)<2200400 < T (K) < 2200,

Cp=3.7782×101T21.7191×106T3+3.0921×103T22.4560T+1.972×103C_p=3.7782\times10^{-1}T^2-1.7191\times10^{-6}T^3+3.0921\times10^{-3}T^2-2.4560T+1.972\times10^3

Cv=1.0369×108T3+3.7164×104T21.0494T+1.5826×103C_v=1.0369\times10^{-8}T^3+3.7164\times10^{-4}T^2-1.0494T+1.5826\times10^3

The R2R^2 values for both fits are 0.997, where the CpC_p fit matches experimental data to within 0.5%, while for CvC_v matches experimental data to within 1.5%.

Enthalpy is computed based on the definition of CpC_p,

Cp(hT)pC_p\equiv\left(\frac{\partial h}{\partial T}\right)_p

Neglecting any variation in the saturation conditions with respect to pressure (i.e. Poynting-type effects), hh can be computed by integrating the above expression,

h(T)h(Tref)=TrefTCpdTh(T)-h(T_{ref})=\int_{T_{ref}}^TC_pdT'

where TrefT_{ref} is a reference temperature and h(Tref)h(T_{ref}) is the enthalpy at that reference temperature. This expression is used to evaluate enthalpy based on the CpC_p fit as

h(T)=F(T)401088.7h(T)=F(T)-401088.7

where F(T)F(T) is the integral of CpC_p with respect to temperature evaluated at TT and 401088.7401088.7 J/kg/K is a constant representing F(Tref)+h(Tref)-F(T_{ref})+h(T_{ref}) selected in order to match the Fink and Leibowitz correlation at 371 K. This approach, rather than simply using the Fink and Leibowitz correlation outright, is used to ensure exact compatibility with thermodynamic definitions and the particular fit for CpC_p selected in this class. Computing hh based on an integral of CpC_p matches the Fink and Leibowitz correlations to within 0.2% over the entire range for which the CpC_p fit is valid.

Range of Validity

These fluid properties correspond to saturated conditions (that is, the sodium is at the saturation pressure).

Input Parameters

  • execute_onTIMESTEP_ENDThe list of flag(s) indicating when this object should be executed. For a description of each flag, see https://mooseframework.inl.gov/source/interfaces/SetupInterface.html.

    Default:TIMESTEP_END

    C++ Type:ExecFlagEnum

    Unit:(no unit assumed)

    Options:NONE, INITIAL, LINEAR, NONLINEAR_CONVERGENCE, NONLINEAR, POSTCHECK, TIMESTEP_END, TIMESTEP_BEGIN, MULTIAPP_FIXED_POINT_END, MULTIAPP_FIXED_POINT_BEGIN, FINAL, CUSTOM

    Controllable:No

    Description:The list of flag(s) indicating when this object should be executed. For a description of each flag, see https://mooseframework.inl.gov/source/interfaces/SetupInterface.html.

  • prop_getter_suffixAn optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.

    C++ Type:MaterialPropertyName

    Unit:(no unit assumed)

    Controllable:No

    Description:An optional suffix parameter that can be appended to any attempt to retrieve/get material properties. The suffix will be prepended with a '_' character.

  • use_interpolated_stateFalseFor the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:For the old and older state use projected material properties interpolated at the quadrature points. To set up projection use the ProjectedStatefulMaterialStorageAction.

Optional Parameters

  • T_initial_guess400Temperature initial guess for Newton Method variable set conversion

    Default:400

    C++ Type:double

    Unit:(no unit assumed)

    Controllable:No

    Description:Temperature initial guess for Newton Method variable set conversion

  • p_initial_guess200000Pressure initial guess for Newton Method variable set conversion

    Default:200000

    C++ Type:double

    Unit:(no unit assumed)

    Controllable:No

    Description:Pressure initial guess for Newton Method variable set conversion

  • tolerance1e-08Tolerance for 2D Newton variable set conversion

    Default:1e-08

    C++ Type:double

    Unit:(no unit assumed)

    Controllable:No

    Description:Tolerance for 2D Newton variable set conversion

Variable Set Conversions Newton Solve Parameters

  • allow_duplicate_execution_on_initialFalseIn the case where this UserObject is depended upon by an initial condition, allow it to be executed twice during the initial setup (once before the IC and again after mesh adaptivity (if applicable).

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:In the case where this UserObject is depended upon by an initial condition, allow it to be executed twice during the initial setup (once before the IC and again after mesh adaptivity (if applicable).

  • allow_imperfect_jacobiansFalsetrue to allow unimplemented property derivative terms to be set to zero for the AD API

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:true to allow unimplemented property derivative terms to be set to zero for the AD API

  • control_tagsAdds user-defined labels for accessing object parameters via control logic.

    C++ Type:std::vector<std::string>

    Unit:(no unit assumed)

    Controllable:No

    Description:Adds user-defined labels for accessing object parameters via control logic.

  • enableTrueSet the enabled status of the MooseObject.

    Default:True

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:Yes

    Description:Set the enabled status of the MooseObject.

  • execution_order_group0Execution order groups are executed in increasing order (e.g., the lowest number is executed first). Note that negative group numbers may be used to execute groups before the default (0) group. Please refer to the user object documentation for ordering of user object execution within a group.

    Default:0

    C++ Type:int

    Unit:(no unit assumed)

    Controllable:No

    Description:Execution order groups are executed in increasing order (e.g., the lowest number is executed first). Note that negative group numbers may be used to execute groups before the default (0) group. Please refer to the user object documentation for ordering of user object execution within a group.

  • force_postauxFalseForces the UserObject to be executed in POSTAUX

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:Forces the UserObject to be executed in POSTAUX

  • force_preauxFalseForces the UserObject to be executed in PREAUX

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:Forces the UserObject to be executed in PREAUX

  • force_preicFalseForces the UserObject to be executed in PREIC during initial setup

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:Forces the UserObject to be executed in PREIC during initial setup

  • fp_typesingle-phase-fpType of the fluid property object

    Default:single-phase-fp

    C++ Type:FPType

    Unit:(no unit assumed)

    Controllable:No

    Description:Type of the fluid property object

  • use_displaced_meshFalseWhether or not this object should use the displaced mesh for computation. Note that in the case this is true but no displacements are provided in the Mesh block the undisplaced mesh will still be used.

    Default:False

    C++ Type:bool

    Unit:(no unit assumed)

    Controllable:No

    Description:Whether or not this object should use the displaced mesh for computation. Note that in the case this is true but no displacements are provided in the Mesh block the undisplaced mesh will still be used.

Advanced Parameters

References

  1. F.E. Dunn. The SAS4A/SASSYS-1 safety analysis code system, chapter 12: sodium voiding model. Technical Report ANL/NE-16/19, Argonne National Laboratory, 2017.[BibTeX]
  2. J.F. Fink and L. Leibowitz. Thermophysical properties of sodium. Technical Report ANL-CEN-RSD-79-1, Argonne National Laboratory, 1979.[BibTeX]